Tonight has so far seen all of the remaining singers perform twice, both a solo number and a duet with their coach.
The vote was frozen and a count taken, which saw Vince leave the competition in fourth place.
It means Bo Bruce, Tyler James and Leanne Mitchell will go on to fight it out for the winning spot later in the show tonight.
The trio will perform their potential winner's songs before the lines close for good.
Speaking to host Holly, Vince said: "It's been a fantastic experience, I've learned a lot.
"Jessie's been more than a coach, she's a really good friend. I'm ready to go now, I've done my album and hopefully I'll get to release it now."
Jessie added: "Sometimes winning isn't everything, the journey is more important than where you end up. Vince is an incredible artist and I'm so happy that I've been a part of this journey.
"I just want to thank The Voice for creating a show that's completely different and enabled so many artists to have a platform to sing."