The 47-year-old from Glasgow impressed the panel with her take on classic track Wild Horses, although only Sir Tom pressed his buzzer to turn around.
Will.i.am explained: "The reason I didn’t turn around is because I know you and Mr. Jones have a thing going on"
Sir tom told her: "You’re a great singer, a wonderful voice, I’m proud to have you on my team"
Barbara replied: “You have always been a legend in my house and family, it's a privilege.”
Watch [tag]Barbara Bryceland[/tag]'s blind audition on The Voice UK below...