Despite the music competition still being around month away from kicking off, the 'Domino' hit maker is the 9/4 favourite to coach one of her acts to victory.
The show sees four current chart toppers create and nurture teams of musical talent, with weekly public eliminations leaving just one singer in each of the four teams for the grand final.
Last week the four coaches whittled down their teams to a final five, who will go on to compete in the live shows in May.
While Jessie is currently tipped to win the first ever series, she faces stiff competition from Black Eyed Peas star Will.i.am, who is second favourite.
The Script's Danny O'Donoghue on the other hand is an outside bet, with punters seemingly not yet convinced of the Irish singer.
The Voice UK will launch on BBC One on March 24.