The 2016 housemate appeared to give pal Charlotte Dawson dating advice.
Sam told Charlotte, who is looking for love on the show: "I think you're becoming a sexual predator to these boys. I think guys are intimidated by you. I think you put on a front, and I think you need to strip that all back."
Charlotte opened up about being hurt in the past and saying she was worried about letting her guard down again.
She then confessed her feelings for fellow celebrity dater, X Factor's Frankie Cocozza.
"You're going to get in trouble," Sam warned.
"But I like trouble!" Charlotte replied.
Alongside Charlotte and Frankie on the Celebs Go Dating line up this year are TOWIE star James ‘Arg’ Argent, Model Calum Best and TOWIE's Bobby Norris.
They're joined by Made In Chelsea's Georgia Toffolo, TV presenter Sarah-Jane Crawford and Hollywood beauty Courtney Stodden.
In this week's episodes, the agents spiced things up as they sent the celebs to sensory speed dating, where they had to rely on much more than their chat to bag a date.
After a pep talk from Charlotte, Sarah-Jane tried to let her fingers do the talking. Calum attempted to master the art of silent seduction, and things got heated between Charlotte and Frankie as they both found new love interests.
Charlotte then headed to Blackpool to try to work out her Frankie dilemma while Arg's date took a turn for the worse.
Series 3 of Celebs Go Dating airs Monday to Friday at 10PM on E4.
This is the final week with the show concluding on Friday night.