The singing duo were one of the first acts booted out on the X Factor last year, but have still secured a record deal.
The girls - Lucy and Charley - have recorded a cover of Turn Me On (Turn Me Out) which will be released in September.
Speaking to DigitalSpy however, the pair revealed they'd be up for more reality telly.
"We're up for anything. We're up for a laugh. We'd like to do Big Brother, I'm A Celeb would be hilarious," Lucy said. "I just think we'd be TV gold. We're scared of everything."
She added: "We're just putting it out there, putting the feelers out. If anyone wants to approach the Shoes, call us, emoshe."
And the former X Factor finalist compared her and pal Charley to singing twins Jedward.
"Jungle would be hilar. I think we'd be fine. We've got each other you see, we'd have to be one contestant - we couldn't be separated. It's like Jedward," she said.
[cat c="big brother 2012"]Celebrity Big Brother 2012[/cat] starts on Channel 5 on August 15.